Initially I thought what "What a ludicrous idea" then I looked at the layout and understood what it's purpose is......
You would need a power source to power the relays.
The only thing I can see is that you would have a footswitchable volume control via that relay from one Master volume pot to the other providing two separate volume settings like rhythm and lead volumes.
The only other option and a more simple option would be to install a 250K(my layout shows 250K)(I have not verified this value) audio pot off the 1 MEG master volume like Splawn used to do with his early modded Marshalls and it does not require a powered relay and it worked great for Splawn. The above complicated setup is interesting but you have a much simpler solution staring you in the face. Just have a tech install the solo boost pot in line with your bright volume pot of your 1959 plexi and be done with it. You would also need to a 1/4" jack to plug a single latching footswitch to engage the solo boost volume pot. Again... very simple no powered relays, there should be layout drawings of Splawn modded Marshalls floating around out there to show you how to do it.
Your PS100 also provides two separate footswitchable volume selections as well why not just use the PS100's capabilities?