The two pairs are inner 2 and outer 2. They are what's called a Push-Pull power amp. When you buy a quad of matched tubes you are biasing to either the inner
or outer set, but if they are matched well they should all be close in the bias they draw. You are basically checking to see how the other set is biased when you switch from the yellow OT wire or the red OT wire. If you set the inner to 60-70mA and the outer read 65-75mA, your fine. If you test one pair biased at 60-70mA and the other are reading
110-120mA, the tubes are mismatched and will not bias evenly across all four. You can lower the bias to get them in range, but it takes the other two down as well
and they would be much cooler. 5 to 10mA difference between each tube in the quad is the norm for most tube sellers. It's much easier than the old days when VH4's came with fixed resistors....
For your Herbert, each duet biases in a pair. 1/6, 2/5 and 3/4. These you have to set all at your target and re-adjust all three again. When you bias one pair it may draw more or less natural plate current than another pair so your bias can go up or down of 1/6 and 2/5 if you have a really hot drawing duet in 3/4 or another tube type.
After a few minutes of adjusting you can usually get them all to balance out at your target. It's like juggling.
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...WELL PUT!!!