Just so I can post the answer to my own problem in case anyone ever searches for this sort of thing again; here's the solution.
I'm using the Ground Control Pro -> Axess Electronics AC-8 -> Bogner Ecstasy 101b Classic head (with the custom Axess cable to control the Bogner).
I wanted to use the 10 button setup on the GCP, not the 4 button - but I wanted to have one stomp ability to turn on any channel plus a boost or FX loop (or standby) without needing instant access buttons.
The hurdle to overcome is that the Bogner switches channels via PC and the boosts, loop and standby are CC changes.
All are on midi channel 16.
Green Channel is PC # 5
Blue Channel is PC # 6
Red Channel is PC # 7
Under 'Expanders' on the GCP, enable the send GCX controller <GCX-2>
(I'm not using a GCX, but this is the workaround to get it to send both PC and CC changes at the same time).
Set the GCX (I think it's default) to have the loops NORMAL, not momentary.
Now, you can hit any button on the GCP, then hold down the top right button to get into edit mode - set the head channel (5, 6, 7) and then hit the Bank Down button and go to
the GCX-2...then step on one of the first four buttons on the top row (1 is for standby, 2 is for FX Loop, 3 is for Boost 1, 4 is for Boost 2).
Get out of edit mode and save the settings and now you can have one button access to control any of the functions of the Bogner head.