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I think these might be a good place to start if you just want to read up -
http://en.wikipedia.org/wiki/Linux
http://www.yolinux.com/TUTORIALS/
http://www.linux-tutorial.info/
http://distrowatch.com/
The wiki entry is just to get a bit of background. The YoLinux site will tell you a LOT about how linux functions in nitty-gritty details. The tutorial site is a nice quick reference guide I think. DistroWatch is a good site for keeping tabs on the current distribution trends and may help you pick out a distribution that you like.
Don't let it all frighten you too much. There's probably a ton of terms/concepts that you'll come across that you might not be familiar with at first. And there's several things that if you're used to using Windows, you'll have to differentiate between. An example of this is that "C: drive" is NOT how they denote the root directory. The root directory is /, and everything branches off of that - /etc, /mnt, /proc, /usr, /bin, etc.... Your primary hard drive is usually mounted at /mnt/hda1/ for example. Most distributions don't let you run as an admin user (root) either. So often you'll have to temporarily become root to make a change to the main filesystem. Certain distros make this easier than others.
Just small things like that.
What I would probably do first is go download the Knoppix live CD and boot your PC with that. It won't change anything on your hard drive and gives you a fully funtional Linux desktop that runs all from the CD. That's how most people get their first taste of Linux. You can kind of explore around that for a while to get your bearings and not really worry about screwing anything up because it's all running from a read-only CD. There are several other GREAT live CDs as well (Ubuntu, Sabayon, STD, MEPIS, etc...) but Knoppix seems to be the most popular since it's the oldest/most stable.
If you're ready to take the plunge and install it on your hard drive, what I would do is probably stick with one of the more popular distributions (Ubuntu, OpenSUSE, Fedora) just because they have the largest community-base and should you run into any difficulty, most likely you'll be able to get answers from them. Plus since they're tested by more people, chances are that many the bugs have been ironed out.
This will get you started using Linux on the Desktop. Now bear in mind while it's a GREAT Operating System for a desktop PC, it's most widely used with NO graphical interface on servers. If you want to do Linux server administration it's probably best that you learn a bit about how it functions on the desktop first just so you get a more user-friendly system to warm up to. Then once you're more comfortable with using it, and once you've learned more about the command line, try tackling a server install/configuration. You can of course put a Graphical desktop environment on a server, but most people don't just to save on the overhead.
There's a TON of great tutorials out there to help you get started and mostly the information is all free. Most of the bigger distributions of linux come with their own specific tutorials as well to help you along your way. Ubuntu is especially good with this -
http://www.ubuntuguide.org/ (and they happen to be my current favorite distro next to Fedora)