You already have the pre pi master volume wired up in the preamp, it's just like the one in the jcm 800, as long as the taper of the pot is good it should work just fine, I like it much better than the ppimv for a circuit like you've got. The ppimv is better for 2 or 3 gain stage preamps imo, it's too over the top with a preamp that hot. So do this, I'll give you a step by step.
1. Disconnect the ppimv. Desolder the two green wires coming off the pot from the power tubes, desolder the two red wires coming off the pot from the output coupling caps, leave the other two red wires going to your output grid resistors on the end of the board in place. Disconnect the other red wire coming off the pot from the eyelet in between the output coupling caps, there should be another wire in that eyelet coming from the bias supply, leave it there. The ppimv should be completley disconnected now, go ahead and yank the pot and all of those pesky wires.
2. Time to add the bias feed resistors, if you've got some 220k thats the standard value, 150k also sounds good and you could even use 100k, anything in that ball park will get you up and running and you could tweak it later. So we'll say 220k for this. Take your first 220k and it goes from one of the output coupling caps to that center eyelet where the wire from the bias supply goes, now do the same with your other 220k , go from the end of the other output coupling cap to the eyelet with the bias supply connection. That area of the board should look like an X now with your bias feed resistors on the side of the board towards the pots and your pi plate resistors (82k and 100k) on the side of the board towards the back of the chassis. So the 220k resistors should meet at the middle eyelet with the wire from the bias supply, the other end of each 220k should connect to it's respective output coupling cap. Those red wires running to your a output grid resistors on the end of the board should still be connected where the bias feed resistors meet the output coupling caps.
That should do it. Good luck, I hope that fixes it for ya